Article Details

Enhanced Fenton-like catalytic performance of Cu-Al/KIT-6 and the key role of O2 in triggering reaction

Oleh   Huihui Wang [-]
Kontributor / Dosen Pembimbing : Lili Zhangb, Chun Hub, Xiangke Wang
Jenis Koleksi : Jurnal elektronik
Penerbit : Lain-lain
Fakultas :
Subjek :
Kata Kunci : Cu-Al/KIT-6, Dissolved oxygen, Fenton-like, Pollutants degradation, Radicals
Sumber : Chemical Engineering Journal journal, www.elsevier.com/locate/cej
Staf Input/Edit : Irwan Sofiyan  
File : 1 file
Tanggal Input : 2020-01-29 14:39:57

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Framework Cu doped Al2O3 dispersed on KIT-6 (Cu-Al/KIT-6) was synthesized by the ultrasonic impregnation method and characterized by multi-technologies. The catalyst performed superior catalytic performance and stability for bisphenol A (BPA) degradation in heterogeneous Fenton-like catalysis. Especially, the effect of O2 and N2 on BPA degradation was detected over Cu-Al/KIT-6 in the presence of hydrogen peroxide (H2O2). DMPO spin-trap electron spin resonance (ESR) experiments indicated that O2 can be activated to produce reactive oxygen species (ROS) by Cu(I) on the surface of Cu-Al/KIT-6. Meanwhile, O2 as an electron acceptor can trigger the reaction at the beginning of reaction, which decreased the consumption of H2O2. In addition, BPA and its intermediate products chelate with Cu(II) to form Cu(II)-phenol complex, resulting in a series of reactions to further promote BPA degradation. These findings provide useful insights into the fundamental theories of Fenton catalysts via interface engineering for practical application.