Article Details

QUEST FOR A SYMMETRIC [C-F-C]+ FLUORONIUM ION IN SOLUTION: A WINDING PATH TO ULTIMATE SUCCESS

Oleh   Maxwell Gargiulo Holl [-]
Kontributor / Dosen Pembimbing : Cody Ross Pitts and Thomas Lectka
Jenis Koleksi : Jurnal elektronik
Penerbit : Lain-lain
Fakultas :
Subjek :
Kata Kunci : Symmetric [C?F?C]+
Sumber : American Chemical Society (ACS)
Staf Input/Edit : Irwan Sofiyan  
File : 1 file
Tanggal Input : 2020-02-14 13:21:37

Generic placeholder image
2020 EJRNL PP Maxwell Gargiulo Holl -1.pdf

Terbatas
» ITB


In this Account, we chronicle our tortuous but ultimately fruitful quest to synthesize a [C?F?C]+ fluoronium ion in solution, thus providing the last piece of the organic halonium ion puzzle. Inspiration for the project can be traced all the way back to the graduate career of the corresponding author, wherein the analogy between a [C?H? C]+ “hydrido” bridge and a hypothetical [C?F?C]+ bridge was first noted. The earliest attempt to construct a bicyclo[5.3.3]tridecane-based fluoronium ion (based on the analogous hydrido bridged cation) proved to be synthetically difficult. A subsequent attempt involving a 1,8-substituted naphthalene ring was theoretically naiv? e in retrospect ....