To achieve sustainable development, biomassmaterials are alternative options for mitigating the problemsassociated with energy and the environment. Recently, solubleanthraquinones in aqueous redoxflow batteries have attractedextensive attention. Inspired by a natural anthraquinone dyenamed alizarin, here we report an affordable, sustainable, andefficient redoxflow battery electrolyte using a derivative ofalizarin, namely, alizarin-3-methyliminodiacetic acid, whichhas been easily synthesized from alizarin on an industrial scale.The battery exhibits an open-circuit voltage of 1.38 V, and themaximum power density exceeds 0.49 W cm?2. Also, thebattery has a stable cycling performance of 350 cycles with a high Coulombic efficiency of 99.6%, energy efficiency of 84.2%,and capacity retention of 99.98% per cycle, 99.97% per hour, and 99.19% per day at 0.1 A cm?2. Moreover, the battery system isenvironmentally friendly and provides novel ideas for biomass-derived green energy-storage systems.