90 ATTACHMENT 91 Attachment A Temperature Contour Simulation Results at Maximum Condition NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 92 Attachment B Pressure Contour Simulation Results at Maximum Condition NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 93 Attachment C NOx Emission Contour Simulation Results at 180 0 CA NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 94 Attachment D CO Emission Contour Simulation Results at 180 0 CA NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 95 Attachment E CO2 Emission Contour Simulation Results at 180 0 CA NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 96 Attachment F H2O Emission Contour Simulation Results at 180 0 CA NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 97 Attachment G Excess O2 Contour Simulation Results at 180 0 CA NH3 0% (+25 0 CA) NH3 10% (+25 0 CA) NH3 20% (+25 0 CA) NH3 30% (+25 0 CA) NH3 40% (+25 0 CA) NH3 50% (+25 0 CA) NH3 60% (+25 0 CA) NH3 70% (+25 0 CA) NH3 80% (+25 0 CA) NH3 90% (+25 0 CA) NH3 100% (+25 0 CA) 98 Attachment H Chemical Reaction Kinetic Mechanism Ansys Chemkin-Pro 99 100 101 Attachment I Reaction and Rate Coefficients Ammonia Chemical Kinetics by Miller et. al. (Miller et al., 1983) Reaction A β E 1 NH3+M=NH2+H+M 1.40E+16 0.0 90,600 *2 NH3+H=NH2+H2 2.46E+13 0.0 17,071 3 NH3+O=NH2+OH 1.50E+12 0.0 6040 †4 NH3+OH=NH2+H2O 3.25E+12 0.0 2120 †5 H+NH2=NH+H2 6.92E+13 0.0 3650 *6 NH2+OH=NH+H2O 4.50E+12 0.0 2200 7 NH2+O2=HNO+OH 4.50E+12 0.0 25,000 †8 O+NH2=HNO+H 6.63E+14 -0.5 0 9 O+NH2=NH+OH 6.75E+12 0.0 0 †10 H+NH=N+H2 3.00E+13 0.0 0 *11 NH+O=NO+H 2.00E+13 0.0 0 12 NH+O=N+OH 1.00E+12 0.5 100 *13 NH+OH=N+H2O 5.00E+11 0.5 2000 †14 NH+OH=H+HNO 2.00E+13 0.0 0 †15 HNO+M=H+NO+M 1.50E+16 0.0 48,680 16 HNO+O=OH+NO 1.00E+11 0.0 0 17 HNO+OH=NO+H2O 3.60E+13 0.0 0 18 HNO+H=H2+NO 5.00E+12 0.0 0 †19 NH+NO=N2O+H 4.33E+14 -0.5 0 20 N2O+O=2NO 1.00E+14 0.0 28,200 21 N2O+O=N2+O2 1.00E+14 0.0 28,200 22 N2O+M=N2+O+M 1.62E+14 0.0 51,600 †23 N2O+H=N2+OH 7.60E+13 0.0 15,200 24 N2O+NH=N2+HNO 1.00E+11 0.5 3000 25 N2H3+O=N2H2+OH 5.00E+12 0.0 5000 26 N2H3+O=NH2+HNO 1.00E+13 0.0 0 27 N2H3+OH=N2H2+H2O 1.00E+13 0.0 1000 28 N2H3+H=NH2+NH2 1.60E+12 0.0 0 29 N2H3+M=N2H2+H+M 3.50E+16 0.0 46,000 30 N2H3+NH=NH2+N2H2 2.00E+13 0.0 0 *31 N2H2+M=NNH+H+M 5.00E+16 0.0 50,000 32 N2H2+O2=NNH+OH 2.00E+13 0.0 1000 33 N2H2+O=NO+NH2 1.00E+13 0.0 0 *34 N2H2+NO=N2O+NH2 3.00E+12 0.0 0 †35 NH+NH2=N2H2+H 5.00E+13 0.0 0 36 N2H2+OH=NNH+H2O 1.00E+13 0.0 1000 *37 N2H2+H=NNH+H2 5.00E+13 0.0 1000 38 N2H2+NH=NNH+NH2 1.00E+13 0.0 1000 39 N2H2+NH2=NH3+NNH 1.00E+13 0.0 1000 40 NH2+NH2=N2H2+H2 5.00E+11 0.0 0 41 NH2+NH2+M=N2H4+M 3.00E+20 -1.0 0 102 42 H+N2H4=H2+N2H3 1.30E+13 0.0 2500 43 NH2+N2H4=NH3+N2H3 3.90E+12 0.0 1500 44 O+N2H4=N2H2+H2O 8.50E+13 0.0 1200 45 OH+N2H4=N2H3+H2O 5.00E+12 0.0 1000 46 N2H3+OH=NH3+HNO 1.00E+12 0.0 15,000 47 NH+NH=N2+H+H 2.54E+13 0.0 0 †48 NH2+HNO=NH3+NO 2.00E+13 0.0 1000 49 NH+H+M=NH2+M 2.00E+16 -0.5 0 50 NO+NH2=HNO+NH 1.00E+13 0.0 40,000 †51 NH2+NO=NNH+OH 8.82E+15 -1.3 0 *52 NH2+NO=N2+H2O 3.78E+15 -1.3 0 53 NH2+NO=HNNO+H 8.00E+13 0.0 28,000 54 HNNO+H=N2O+H2 2.00E+13 0.0 0 55 HNNO+O=OH+N2O 2.00E+13 0.0 0 56 HNNO+OH=N2O+H2O 2.00E+13 0.0 0 *57 NH+O2=HNO+O 1.00E+13 0.0 12,000 58 NH+O2=NO+OH 1.40E+11 0.0 2000 59 HNO+HNO=N2O+H2O 3.95E+12 0.0 5000 60 HNO+NO=N2O+OH 2.00E+12 0.0 26,000 61 HNNO+NO=HNO+N2O 2.00E+12 0.0 5000 *62 NNH+NO=N2+HNO 5.00E+13 0.0 0 63 NNH+H=N2+H2 3.70E+13 0.0 3000 64 NNH+O=N2+OH 1.00E+13 0.0 5000 65 NNH+OH=N2+H2O 3.00E+13 0.0 0 66 NNH+O=N2O+H 1.00E+13 0.0 3000 67 OH+N2O=N2+HO2 1.00E+12 0.0 10,000 68 NNH+NH2=N2+NH3 1.00E+13 0.0 0 69 NH2+NH2=NH3+NH 5.00E+12 0.0 10,000 *70 NNH+M=N2+H+M 2.00E+14 0.0 20000 71 NNH+O2=N2+HO2 2.00E+12 0.0 9000 72 NO+HO2=HNO+O2 5.00E+11 0.0 15,000 73 H+NO2=NO+OH 3.50E+14 0.0 1500 74 HO2+NO=NO2+OH 2.11E+12 0.0 -479 75 O+NO2=NO+O2 1.00E+13 0.0 600 76 NO2+M=NO+O+M 1.10E+16 0.0 66,000 77 H2+O2=2OH 1.70E+13 0.0 47,780 †78 OH+H2=H2O+H 1.17E+09 1.3 3626 †79 H+O2=OH+O 5.13E+16 -0.8 16,507 †80 O+H2=OH+H 1.80E+10 1.0 8826 81 H+O2+M=HO2+M 2.10E+18 -1.0 0 82 H+O2+N2=HO2+N2 6.70E+19 -1.4 0 83 H+O2+O2=HO2+O2 6.70E+19 -1.4 0 84 OH+HO2=H2O+O2 5.00E+13 0.0 1000 85 H+HO2=2OH 2.50E+14 0.0 1900 86 O+HO2=O2+OH 4.80E+13 0.0 1000 †87 2OH=O+H2O 6.00E+08 1.3 0 103 88 H2+M=H+H+M 2.23E+12 0.5 92,600 89 O2+M=2O+M 1.85E+11 0.5 95,560 90 H+OH+M=H2O+M 7.50E+23 -2.6 0 91 H+HO2=H2+O2 2.50E+13 0.0 700 92 HO2+HO2=H2O2+O2 2.00E+12 0.0 0 93 H2O2+M=OH+OH+M 1.30E+17 0.0 45,500 94 H2O2+H=HO2+H2 1.60E+12 0.0 3800 95 H2O2+OH=H2O+HO2 1.00E+13 0.0 18,000 †96 O+N2=NO+N 1.84E+14 0.0 76,250 †97 N+O2=NO+O 6.40E+09 1.0 6280 †98 H+NO=N+OH 2.22E+14 0.0 50,500.